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Method 1:

  1. Go to the Control Panel.
  2. Locate and open the Control Panel > Network and Internet > Internet Options item.
  3. Switch to the Security tab.
  4. Click on ‘Restricted sites’ icon and click the Sites button:

    The ‘Restricted sites’ dialog will appear on the screen.

  5. Type the following in the text box and then press the Add button:
  6. Close Internet Options and restart Skype.

The alternative way is as follows: (Method 2)

  1. Go to the following path and edit the hosts file.


  2. Paste the following text in the end of the file: live.rads.msn.com ads1.msn.com static.2mdn.net g.msn.com a.ads2.msads.net b.ads2.msads.net ad.doubleclick.net ac3.msn.com rad.msn.com msntest.serving-sys.com bs.serving-sys.com flex.msn.com ec.atdmt.com cdn.atdmt.com db3aqu.atdmt.com cds26.ams9.msecn.net sO.2mdn.net aka-cdn-ns.adtech.de secure.flashtalking.com adnexus.net adnxs.com *.rad.msn.com *.msads.net *.msecn.net

This will disable ads in Skype and all other Microsoft ads in other software like Office Starter.



Note: collected from http://bit.ly/2fthsZH
For educational purpose only